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单词 Point symmetry group
释义

Point symmetry group

英语百科

Molecular symmetry

Symmetry elements of formaldehyde. C2 is a two-fold rotation axis. σv and σv' are two non-equivalent reflection planes.
XeF4, with square planar geometry, has 1 C4 axis and 4 C2 axes orthogonal to C4. These five axes plus the mirror plane perpendicular to the C4 axis define the D4h symmetry group of the molecule.

Molecular symmetry in chemistry describes the symmetry present in molecules and the classification of molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can predict or explain many of a molecule's chemical properties, such as its dipole moment and its allowed spectroscopic transitions (based on selection rules such as the Laporte rule). Many university level textbooks on physical chemistry, quantum chemistry, and inorganic chemistry devote a chapter to symmetry.

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