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单词 Dihydroxylation
释义

Dihydroxylation

英语百科

Dihydroxylation

Mechanism for dihydroxylation using osmium tetroxide.
Mnemonic for the Sharpless asymmetric dihydroxylation.

Dihydroxylation is the process by which an alkene is converted into a vicinal diol. Although there are many routes to accomplish this oxidation, the most common and direct processes use a high-oxidation-state transition metal (typically osmium or manganese). The metal is often used as a catalyst, with some other stoichiometric oxidant present. In addition, other transition metals and non-transition metal methods have been developed and used to catalyze the reaction.

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