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单词 CPMAS
释义

CPMAS

英语百科

Magic angle spinning

Magic-angle spinning: The sample (blue) is rotating with high frequency inside the main magnetic field (B0). The axis of rotation is tilted by the magic angle θm with respect to the direction of B0.

In nuclear magnetic resonance, magic-angle spinning (MAS) is a technique often used to perform experiments in solid-state NMR spectroscopy.

By spinning the sample (usually at a frequency of 1 to 100 kHz) at the magic angle θm (ca. 54.74°, where cosθm=1/3) with respect to the direction of the magnetic field, the normally broad lines become narrower, increasing the resolution for better identification and analysis of the spectrum.

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