Polyhedral skeletal electron pair theory

Molecular-orbital (MO) diagram of B2H6. Atoms and their corresponding orbitals are colored the same. Green MOs symbolize bonding, while red symbolize anti-bonding.

In chemistry the polyhedral skeletal electron pair theory provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade and were further developed by Michael Mingos and others; they are sometimes known as Wade's rules or the Wade–Mingos rules. The rules are based on a molecular orbital treatment of the bonding. These rules have been extended and unified in the form of the Jemmis mno rules.

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释义	Closo 英语百科 Polyhedral skeletal electron pair theory In chemistry the polyhedral skeletal electron pair theory provides electron counting rules useful for predicting the structures of clusters such as borane and carborane clusters. The electron counting rules were originally formulated by Kenneth Wade and were further developed by Michael Mingos and others; they are sometimes known as Wade's rules or the Wade–Mingos rules. The rules are based on a molecular orbital treatment of the bonding. These rules have been extended and unified in the form of the Jemmis mno rules.
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Polyhedral skeletal electron pair theory