圈烯




圈烯(circulene)即尾部相稠合的邻并苯,是“拱形芳烃”(geodesic polyarene)的一类。[5]圈烯(碗烯)、[6]圈烯(蒄)、[7]圈烯 与[12]圈烯(凯库勒烯)都已合成。[5]圈烯为碗形,[6]圈烯为平面结构,[7]圈烯则具类似马鞍的特殊结构(类比杯芳烃)。
单词 | Circulene |
释义 |
Circulene
中文百科
圈烯![]() ![]() ![]() ![]() 圈烯(circulene)即尾部相稠合的邻并苯,是“拱形芳烃”(geodesic polyarene)的一类。[5]圈烯(碗烯)、[6]圈烯(蒄)、[7]圈烯 与[12]圈烯(凯库勒烯)都已合成。[5]圈烯为碗形,[6]圈烯为平面结构,[7]圈烯则具类似马鞍的特殊结构(类比杯芳烃)。
英语百科
Circulene 圈烯![]() ![]() ![]() ![]() A circulene is a macrocyclic arene in which a central n-sided polygon is completely surrounded and fused by benzenoids. [5]circulene (corannulene), [6]circulene (coronene), [7]circulene, and [12]circulene (kekulene) have all been synthesized in the laboratory. These compounds belong to a larger class of geodesic polyarenes. Whereas [5]circulene is bowl-shaped and [6]circulene is planar, [7]circulene has a unique saddle-shaped structure (compare to cones and partial cones in calixarenes). Conceptually related compounds are the helicenes. |
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