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单词 Trispyrazolylborate
释义

Trispyrazolylborate

英语百科

Trispyrazolylborate

Idealized structure of a Tp ligand bound to a metal center MLn.
Two of several resonance structures for trispyrazolylborate.
Structure of the piano stool complex TpBn,MeMo(CO)2NO.
Structure of the anionic piano stool complex [TpMeMo(CO)3]− together with the counterion [NEt4]+.

In inorganic chemistry, the trispyrazolylborate ligand, abbreviated Tp, is an anionic tridentate and tripodal ligand. Trispyrazolylborate refers specifically to the anion [HB(C3N2H3)3], but the term trispyrazolylborate refers to derivatives substituted at on the pyrazolyl rings. This family of compounds are sometimes called scorpionate ligands.

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