立体选择性 Stereoselectivity
立体选择性,立体化学术语。 当一个反应生成A, B两个立体异构体,而A产量比B多的时候称相应的反应具有立体选择性。典型的立体选择性反应,比如有维蒂希反应,Horner-Wadsworth-Emmons反应,羟醛反应等等。
单词 | Stereoconvergence |
释义 |
Stereoconvergence
中文百科
立体选择性 Stereoselectivity(重定向自Stereoconvergence)
立体选择性,立体化学术语。 当一个反应生成A, B两个立体异构体,而A产量比B多的时候称相应的反应具有立体选择性。典型的立体选择性反应,比如有维蒂希反应,Horner-Wadsworth-Emmons反应,羟醛反应等等。
英语百科
Stereoselectivity 立体选择性(重定向自Stereoconvergence)
![]() ![]() ![]() ![]() In chemistry, stereoselectivity is the property of a chemical reaction in which a single reactant forms an unequal mixture of stereoisomers during the non-stereospecific creation of a new stereocenter or during the non-stereospecific transformation of a pre-existing one. The selectivity arises from differences in steric effects and electronic effects in the mechanistic pathways leading to the different products. Stereoselectivity can vary in degree but it can never be total since the activation energy difference between the two pathways is finite. However, in favorable cases, the minor stereoisomer may not be detectable by the analytic methods used. |
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