Polyfluorene

（重定向自Polyfluorenes）

The fluorene molecule is most commonly linked at the 2 and 7 positions in polyfluorene derivatives. Also, the 9 position is typically where side chains are attached.

This is the photoluminescence of two very similarly structured polyfluorene derivatives. The one on the left (purple) is a copolymerization of a fluorene derivative, benzene and oxadiazole molecules and the one on the right (light green) has the structure directly below this image.

This polyfluorene derivative photoluminesces light green (the vial on the right in the image above), the alcohol (-OH) side chains can participate in ESIPT with the neighboring oxadiazole nitrogens causing a red-shifted emission. The meta-linkages in the backbone impart solubility in lieu of multiple side chains.

Polyfluorenes are a class of polymeric materials. They are of interest because similar to other conjugated polymers, they are currently being investigated for use in light-emitting diodes, field-effect transistors, and plastic solar cells. They are not a naturally occurring material, but are designed and synthesized for their applications. Modern chemistry has enabled adaptable synthesis and control over polyfluorenes that has facilitated use in many organic electronic applications.

单词	Polyfluorenes
释义	Polyfluorenes 英语百科 Polyfluorene （重定向自Polyfluorenes） Polyfluorenes are a class of polymeric materials. They are of interest because similar to other conjugated polymers, they are currently being investigated for use in light-emitting diodes, field-effect transistors, and plastic solar cells. They are not a naturally occurring material, but are designed and synthesized for their applications. Modern chemistry has enabled adaptable synthesis and control over polyfluorenes that has facilitated use in many organic electronic applications.
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