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单词 Perkov reaction
释义

Perkov reaction

中文百科

Perkow反应 Perkow reaction

(重定向自Perkov reaction)

Perkow反应(Perkow reaction)

亚磷酸三烷基酯与卤代酮反应生成烯基二烷基磷酸酯和卤代烃。

此反应常为 Michaelis-Arbuzov 反应的副反应。

英语百科

Perkow reaction Perkow反应

(重定向自Perkov reaction)

The Perkow reaction is an organic reaction in which a trialkyl phosphite ester reacts with a haloketone to form a dialkyl vinyl phosphate and an alkyl halide.

In the related Michaelis–Arbuzov reaction the same reactants are known to form a beta-keto phosphonate which is an important reagent in the Horner–Wadsworth–Emmons reaction on the road to alkenes. The Perkow reaction, in this respect is considered a side-reaction.

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