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单词 Jones oxidation
释义

Jones oxidation

中文百科

琼斯氧化反应

琼斯氧化反应Jones氧化)是铬酸在丙酮中将一级和二级醇分别氧化为羧酸和酮的反应。

反应放热、迅速,产率也较高。该反应中的氧化剂也称Jones试剂,即三氧化铬在浓硫酸中的溶液。

反应条件下醛也会被氧化为羧酸。但双键一般不被氧化。

英语百科

Jones oxidation 琼斯氧化反应

The Jones oxidation is an organic reaction for the oxidation of primary and secondary alcohols to carboxylic acids and ketones, respectively. It is named after its discoverer, Sir Ewart Jones.

Jones reagent is a solution of chromium trioxide in dilute sulfuric acid and acetone. A mixture of potassium dichromate and dilute sulfuric acid can also be used. The solvent acetone markedly affects the properties of the chromic acid. The oxidation is very rapid, quite exothermic, and the yields are typically high. The reagent rarely oxidizes unsaturated bonds.

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