The turnover-limiting step for the asymmetric allylic oxidation is the formation of chiralcatalyst-allyl perbenzoate complexes.
其中催化剂-苯甲酸丁烯酯手性加合物的生成是反应产物的手性决定步骤。
2
The reaction condition is bland, operation is simple, synthesis of chiralcatalyst is simple, and activity is high, it is adequate for industrial generation.
该方法具有反应条件温和,操作简便,所用手性催化剂合成简单,且活性高,适于工业化应用。
3
Chiral amino alcohol is a kind of the ligand or catalyst with great potential for the development of catalytic asymmetric synthesis.