化学

• 碳硼烷

  In this paper, the following aspects were included.1. A series of Ru carbene catalysts containing a closo-1, 2-carborane, or an anionic nido-7, 8-C2B9H11 tag were developed, and their catalytic activities were carefully investigated for the ring-closing metathesis reactions.

  本论文在以下几个方面做了具体的研究工作:1.首次将碳硼烷用于钌卡宾催化剂的设计合成中,通过一系列反应合成了闭环和开环碳硼烷修饰的钌卡宾催化剂,并对催化剂的催化活性进行了测试。