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单词 allyl
释义

Definition of allyl in English:

allyl

noun ˈalɪlˈalʌɪlˈaləl
Chemistry
  • as modifier Of or denoting the unsaturated hydrocarbon radical —CH₂CH=CH₂

    〔化〕烯丙基

    allyl alcohol

    烯丙醇。

    Example sentencesExamples
    • Garlic and onions are medicinal for their allyl sulphides antioxidant and detoxifying activity.
    • The biosynthesis of many important primary metabolites (such as cholesterol) proceed through intermediates that contain the allyl alcohol functional group.
    • Initially our efforts concentrated on the two allyl side chains attached to the heterocycle via a methylene group.
    • The onion family (including leeks, chives and scallions) is rich in allyl sulfides, which can help lower high blood pressure and show promise in protecting against cancers of the stomach and the digestive tract.
    • Epichlorohydrin is an important epoxide whose creation comes mainly from hydrochlorination of allyl chloride.

Derivatives

  • allylic

  • adjective əˈlɪlɪk
    Chemistry
    • An example that Blackmond often uses is the asymmetric hydrogenation of the allylic alcohols geraniol and its isomers (g geraniol and nerol) carried out while she was at Merck.
      Example sentencesExamples
      • For substances containing allyl or allylic side chains a direct mechanism of action involving an allylic cation which then reacts with nucleophilic centers of nucleic acid bases has been discussed in the literature.
      • Abstraction of the double allylic hydrogen of CDH by triplet BZP would lead to a radical pair; this could explain the formation of benzene and all the detected minor photoproducts.
      • Decomposition of these primary photoproducts to give secondary products arising from allylic hydroperoxide degradation - either by Hock rearrangement or by alkenyl ether epoxidation - was also observed.
      • In complementary experiments, CHD and CHDCA were used as models for LA as they also have double allylic systems.

Origin

Mid 19th century: from Latin allium 'garlic' + -yl.

Definition of allyl in US English:

allyl

nounˈaləl
Chemistry
  • as modifier The unsaturated hydrocarbon radical —CH=CHCH₂

    〔化〕烯丙基

    allyl alcohol

    烯丙醇。

    Example sentencesExamples
    • The onion family (including leeks, chives and scallions) is rich in allyl sulfides, which can help lower high blood pressure and show promise in protecting against cancers of the stomach and the digestive tract.
    • Epichlorohydrin is an important epoxide whose creation comes mainly from hydrochlorination of allyl chloride.
    • The biosynthesis of many important primary metabolites (such as cholesterol) proceed through intermediates that contain the allyl alcohol functional group.
    • Garlic and onions are medicinal for their allyl sulphides antioxidant and detoxifying activity.
    • Initially our efforts concentrated on the two allyl side chains attached to the heterocycle via a methylene group.

Origin

Mid 19th century: from Latin allium ‘garlic’ + -yl.

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更新时间:2024/12/27 18:29:56