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单词 enthalpy
释义

Definition of enthalpy in English:

enthalpy

nounˈɛnθ(ə)lpiɛnˈθalpi
Physics
  • 1A thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume.

    〔物理〕焓,热函(符号: H

    Example sentencesExamples
    • The internal energy of a system, like the enthalpy, is a state property, so it is fixed when the state of the system is specified.
    • Unlike enthalpies, component entropies are nonadditive.
    • We have modeled the closing kinetics and in so doing have obtained stacking enthalpies and entropies for single-stranded nucleic acids.
    • Thermogram transition temperatures, enthalpies, and widths at half-height were determined using the software provided with the calorimeter.
    • Scanning calorimetry is used as a direct method to reveal the thermodynamic properties of phase transition like transition temperatures and enthalpies.
    1. 1.1 The change in enthalpy associated with a particular chemical process.
      (与特定的化学反应过程相关的)焓变
      most compounds have negative enthalpies of formation
      Example sentencesExamples
      • In addition, melting requires significant amounts of extra heat, (in thermodynamic terms, the enthalpy of fusion), to break molecular bonds and cause a phase transition from solid to liquid.
      • The positive correlations lend support to the claim that a coupling free energy may reflect a state in which enthalpy and entropy components compensate for each other.
      • So, we can get useful work out of a system by reducing enthalpy or by increasing entropy (increasing the amount of disorder).
      • First, the volume change and the enthalpy change of the protein can be determined in time domain without temperature variation or solvent variation method.
      • The enthalpy, entropy, and free energy changes in the opening reaction of each basepair are determined from the temperature dependence of the exchange rates.

Origin

1920s: from Greek enthalpein 'warm in', from en- 'within' + thalpein 'to heat'.

Definition of enthalpy in US English:

enthalpy

noun
Physics
  • 1A thermodynamic quantity equivalent to the total heat content of a system. It is equal to the internal energy of the system plus the product of pressure and volume.

    〔物理〕焓,热函(符号: H

    Example sentencesExamples
    • Scanning calorimetry is used as a direct method to reveal the thermodynamic properties of phase transition like transition temperatures and enthalpies.
    • Unlike enthalpies, component entropies are nonadditive.
    • The internal energy of a system, like the enthalpy, is a state property, so it is fixed when the state of the system is specified.
    • We have modeled the closing kinetics and in so doing have obtained stacking enthalpies and entropies for single-stranded nucleic acids.
    • Thermogram transition temperatures, enthalpies, and widths at half-height were determined using the software provided with the calorimeter.
    1. 1.1 The change in enthalpy associated with a particular chemical process.
      (与特定的化学反应过程相关的)焓变
      most compounds have negative enthalpies of formation
      Example sentencesExamples
      • In addition, melting requires significant amounts of extra heat, (in thermodynamic terms, the enthalpy of fusion), to break molecular bonds and cause a phase transition from solid to liquid.
      • First, the volume change and the enthalpy change of the protein can be determined in time domain without temperature variation or solvent variation method.
      • So, we can get useful work out of a system by reducing enthalpy or by increasing entropy (increasing the amount of disorder).
      • The enthalpy, entropy, and free energy changes in the opening reaction of each basepair are determined from the temperature dependence of the exchange rates.
      • The positive correlations lend support to the claim that a coupling free energy may reflect a state in which enthalpy and entropy components compensate for each other.

Origin

1920s: from Greek enthalpein ‘warm in’, from en- ‘within’ + thalpein ‘to heat’.

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更新时间:2024/11/10 1:00:18